We want to find
$\dfrac{d}{dx}\left(\int_{\sin^2 x}^{2\sin x} e^{t^2}, dt\right)$ at $x=\pi$.
Using Leibniz rule:
$\dfrac{d}{dx}\left(\int_{a(x)}^{b(x)} f(t) dt\right)
= f(b(x)) b'(x) ;-; f(a(x)) a'(x)$
Here
$a(x)=\sin^2 x$,
$b(x)=2\sin x$,
$f(t)=e^{t^2}$.
Compute derivatives:
$a'(x)=2\sin x\cos x$
$b'(x)=2\cos x$
So the derivative is:
$e^{(2\sin x)^2}(2\cos x)-e^{(\sin^2 x)^2}(2\sin x\cos x)$
Now evaluate at $x=\pi$
$\sin\pi=0,\quad \cos\pi=-1$
Thus:
$b'(\pi)=2(-1)=-2$
$a'(\pi)=0$
Therefore:
$e^{0}(-2)-e^{0}(0)=-2$
So the final answer is:
$-2$